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Properties of Stoichiometric LiNbO3
Properties  
【Stoichiometric】
 LiNbO3 (SLN)
Crystal system  
Trigonal
Space group  
R3c
Curie temperture
Tc C)
〜1200
〜1220(MgO doped)
[Li2O]:[Nb2O5] mol ratio
(estimated from Tc)
 
49.9:50.1
Lattice parameters 
          
c0 (nm)
0.51482
a0 (nm)
1.3857
Absorption edge 1                    data
nm
305
Refractive indices 
(@633nm)    
no
2.2865
ne
2.1898
Birefringence    
no-ne
0.0967
Linear EO constants 2 
r33 (pm/V)
29.0 at 633nm
Nonlinear optical constants 3
              
d31 (pm/V)
4.7
d33(pm/V)
23.8
Domain switching E-field4             data
(coercive field)
Ec(kV/mm)
< 4
Thermal conductivity 5                data
W/(m・K)
5.97
5.62 (MgO doped)
Laser damage threshold (MgO doped only)
GW/cm2
〜14 (at 1053nm, 1ns pulse)
Photorefractive damage threshold 6     data
(MgO doped only)
MW/cm2
2 (at 532nm, cw)
GRIIRA 7                            data
ppm/cm2
〜300
          
1 Y. Furukawa et al., "Improved Properties of Stoichiometric LiNbO3 for Electro-Optic Applications", J. Intel. Mat. Sys. Struc. 10, p.470(1999)
2 S. Mori et al., The 55th Spring Meeting, 2008, The Jpn. Soc. Appl.Phys. 28a-ZG-4, p.1222 (2008)
3 I. Shoji et al., The 67th Autumn Meeting, 2006, The Jpn. Soc. Appl. Phys. 30p-ZX-2, p.1080 (2006)
4 V. Gopalan et al. "The role of nonstoichiometry in 180°domain switching of LiNbO3 crystals", Appl. Phys. Lett. 72, p.1981 (1998)
5 K. Kitamura et al., Oyo buturi 74, p.573 (2005)
6 Y. Furukawa et al., "Stoichiometric Mg:LiNbO3 as an effective material for nonlinear optics", Opt. Lett. 23, p.1981 (1998)
7 Y. Furukawa et al., "Elimination of photorefraction and green-induced-infrared-absorption in MgO-doped near-stoichiometric LiNbO3"
 Topical meeting on Advanced Solid-State Lasers (ASSL), p.480 (2000)
          
          
          
◆Absorption spectra
◆Switching fields


◆Thermal conductivity

◆Photorefractive damage threshold



◆GRIIRA

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